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Ionic liquids in cross-coupling reactions: “liquid” solutions to a “solid” precipitation problem

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Abstract

To alleviate the problem of solid salt precipitation when using inorganic bases in cross-coupling reactions, basic anions were combined with the trihexyl(tetradecyl)phosphonium ([P66614]+) cation to ensure an ionic liquid byproduct. If the starting base is also an ionic liquid, as is the case for [P66614][OH]·4MeOH, it can be used as both base and solvent.

Graphical abstract: Ionic liquids in cross-coupling reactions: “liquid” solutions to a “solid” precipitation problem

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Publication details

The article was received on 17 Dec 2017, accepted on 31 Jan 2018 and first published on 31 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC09635F
Citation: Chem. Commun., 2018, Advance Article
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    Ionic liquids in cross-coupling reactions: “liquid” solutions to a “solid” precipitation problem

    H. Choudhary, P. Berton, G. Gurau, A. S. Myerson and R. D. Rogers, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC09635F

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