Issue 17, 2018
From the journal:

Chemical Communications

Palladium-catalyzed hydroformylation of terminal arylacetylenes with glyoxylic acid†

Yang Liu, ORCID logo a   Liangzhen Cai, ORCID logo *a   Sheng Xu, ORCID logo *a   Weiwen Pu ORCID logo a  and  Xiaochun Tao ORCID logo *a  

* Corresponding authors

a School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Mei Long Road, Shanghai 200237, China
E-mail: xusheng@ecust.edu.cn, xctao@ecust.edu.cn

Abstract

A simple, practical and governable palladium-catalyzed hydroformylation of terminal arylacetylenes has been disclosed. The reaction proceeds under syngas-free conditions, using readily available glyoxylic acid as the formyl source, under mild conditions, giving rise to a broad range of α,β-unsaturated aldehydes.

Graphical abstract: Palladium-catalyzed hydroformylation of terminal arylacetylenes with glyoxylic acid

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Article information

DOI
https://doi.org/10.1039/C7CC09629A
Article type
Communication
Submitted
18 Dec 2017
Accepted
25 Jan 2018
First published
31 Jan 2018

Chem. Commun., 2018,54, 2166-2168

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Palladium-catalyzed hydroformylation of terminal arylacetylenes with glyoxylic acid

Y. Liu, L. Cai, S. Xu, W. Pu and X. Tao, Chem. Commun., 2018, 54, 2166 DOI: 10.1039/C7CC09629A

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