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Issue 28, 2018
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Synthesis and characterization of an Fe(I) cage complex with high stability towards strong H-acids

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Abstract

The first synthesized and X-ray structurally characterized “classical” iron(I) dioximate showed an unrivaled stability towards strong acids, thus calling for a reassessment of the origins of the electrocatalytic activity of similar low-valent cobalt and iron cage complexes with electron-withdrawing ribbed substituents, shown previously to be effective electrocatalysts of the HER.

Graphical abstract: Synthesis and characterization of an Fe(i) cage complex with high stability towards strong H-acids

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The article was received on 18 Dec 2017, accepted on 31 Jan 2018 and first published on 31 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC09611A
Citation: Chem. Commun., 2018,54, 3436-3439
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    Synthesis and characterization of an Fe(I) cage complex with high stability towards strong H-acids

    Y. Z. Voloshin, V. V. Novikov, Y. V. Nelyubina, A. S. Belov, D. M. Roitershtein, A. Savitsky, A. Mokhir, J. Sutter, M. E. Miehlich and K. Meyer, Chem. Commun., 2018, 54, 3436
    DOI: 10.1039/C7CC09611A

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