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Controlling orthogonal self-assembly through cistrans isomerization of a non-covalent palladium complex dimer

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Abstract

The trans-configured square-planar complex of dichloropalladium and chiral monodentate phosphine ligands forms self-complementary dimers through 16 hydrogen bonded amides and π–π stacking in chlorinated solvents. The self-assembly is controlled by cistrans isomerisation of the metal center, where the trans-configuration governs the dimer formation.

Graphical abstract: Controlling orthogonal self-assembly through cis–trans isomerization of a non-covalent palladium complex dimer

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Publication details

The article was received on 13 Dec 2017, accepted on 29 Dec 2017 and first published on 02 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC09537F
Citation: Chem. Commun., 2018, Advance Article
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    Controlling orthogonal self-assembly through cistrans isomerization of a non-covalent palladium complex dimer

    Z. Kokan, B. Kovačević, Z. Štefanić, P. Tzvetkova and S. I. Kirin, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC09537F

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