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A giant M2L3 metallo-organic helicate based on phthalocyanines as a host for electroactive molecules

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Abstract

An unprecedented Fe2Pc3 metallo-organic helicate has been assembled using a bidentate phthalocyanine (Pc) ligand, 2-formylpyridine and Fe(OTf)2. This giant helicate has proved itself as a host for large redox-active guests such as fullerene and naphthalenediimide derivatives. Photoactivated electronic interactions between components occur in the host–guest complex.

Graphical abstract: A giant M2L3 metallo-organic helicate based on phthalocyanines as a host for electroactive molecules

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Publication details

The article was received on 12 Dec 2017, accepted on 11 Feb 2018 and first published on 12 Feb 2018


Article type: Communication
DOI: 10.1039/C7CC09528G
Citation: Chem. Commun., 2018, Advance Article
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    A giant M2L3 metallo-organic helicate based on phthalocyanines as a host for electroactive molecules

    E. Fazio, C. J. E. Haynes, G. de la Torre, J. R. Nitschke and T. Torres, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC09528G

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