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Issue 31, 2018
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Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction

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Abstract

The first example of a CNC pincer ligand with a central pyridinol ligand is reported in a nickel(II) complex. This metal complex can be protonated or deprotonated reversibly in situ to switch on or off the photocatalytic performance towards CO2 reduction. The O substituent appears essential for catalysis.

Graphical abstract: Nickel(ii) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction

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Publication details

The article was received on 11 Dec 2017, accepted on 13 Mar 2018 and first published on 13 Mar 2018


Article type: Communication
DOI: 10.1039/C7CC09507D
Citation: Chem. Commun., 2018,54, 3819-3822
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    Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction

    D. B. Burks, S. Davis, R. W. Lamb, X. Liu, R. R. Rodrigues, N. P. Liyanage, Y. Sun, C. E. Webster, J. H. Delcamp and E. T. Papish, Chem. Commun., 2018, 54, 3819
    DOI: 10.1039/C7CC09507D

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