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A mononuclear manganese(III)–hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

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Abstract

We report the synthesis of manganese(III)–peroxo (MnIII(O2)) and manganese(III)–hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(III)–hydroperoxo complex in electrophilic and nucleophilic reactions.

Graphical abstract: A mononuclear manganese(iii)–hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

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Publication details

The article was received on 11 Dec 2017, accepted on 07 Jan 2018 and first published on 08 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC09492B
Citation: Chem. Commun., 2018, Advance Article
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    A mononuclear manganese(III)–hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

    M. Sankaralingam, Y. Lee, S. H. Jeon, M. S. Seo, K. Cho and W. Nam, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC09492B

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