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Quinoline-para-quinones and metals: coordination-assisted formation of quinoline-ortho-quinones

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Abstract

The reaction of the para-quinone 6,7-dichloroquinoline-5,8-dione with various transition metal dimers led to the unexpected formation of quinoline-ortho-quinone metal complexes. Systematic variation of the reaction conditions helped identify the solvent as the source of the carbonyl oxygen.

Graphical abstract: Quinoline-para-quinones and metals: coordination-assisted formation of quinoline-ortho-quinones

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Publication details

The article was received on 11 Dec 2017, accepted on 27 Dec 2017 and first published on 11 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC09478G
Citation: Chem. Commun., 2018, Advance Article
  • Open access: Creative Commons BY license
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    Quinoline-para-quinones and metals: coordination-assisted formation of quinoline-ortho-quinones

    M. Kubanik, N. Y. S. Lam, H. U. Holtkamp, T. Söhnel, R. F. Anderson, S. M. F. Jamieson and C. G. Hartinger, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC09478G

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