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Synthesis of Bench-Stable Solid Triorganoindium Reagents and Reactivity in Palladium-Catalyzed Cross-Coupling Reactions

Abstract

Bench-stable solid triorganoindium compounds have been prepared by coordination with 4-(dimethylamino)pyridine (DMAP). The solid R3In(DMAP) complexes are obtained from the corresponding solution of R3In in quantitative yield and can be stored for up to several weeks. These reagents show excellent reactivity in palladium-catalyzed cross-coupling reactions with organic electrophiles.

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Publication details

The article was received on 05 Dec 2017, accepted on 11 Jan 2018 and first published on 12 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC09344F
Citation: Chem. Commun., 2018, Accepted Manuscript
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    Synthesis of Bench-Stable Solid Triorganoindium Reagents and Reactivity in Palladium-Catalyzed Cross-Coupling Reactions

    J. M. Gil-Negrete, J. Pérez Sestelo and L. Sarandeses, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C7CC09344F

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