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Synthesis of functionalized helical BN-benzo[c]phenanthrenes

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Abstract

A novel parent BN-benzo[c]phenanthrene, with helical chirality and remarkable structural features, has been easily obtained in three steps with a global yield of 55%. Moreover, Cl-substituted derivatives have been prepared and these have served as useful starting materials for the development of palladium-catalyzed cross-coupling reactions.

Graphical abstract: Synthesis of functionalized helical BN-benzo[c]phenanthrenes

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Publication details

The article was received on 02 Dec 2017, accepted on 03 Jan 2018 and first published on 03 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC09264D
Citation: Chem. Commun., 2018, Advance Article
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    Synthesis of functionalized helical BN-benzo[c]phenanthrenes

    A. Abengózar, P. García-García, D. Sucunza, A. Pérez-Redondo and J. J. Vaquero, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC09264D

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