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The homometallic polyoxotungstate archetype {P4W24}

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Abstract

Functionalization with terminal organophosphonate and -arsonate groups allows for crystallization and structural characterization of elusive homometallic phosphotungstates of the {PV4WVI24} archetype. 31P NMR measurements reveal moderate stability in aqueous solution for the [(PhPO)2P4W24O92]16− derivative, enabling consecutive reactions as exemplified by the formation of a CoII-{P4W24}-based coordination polymer.

Graphical abstract: The homometallic polyoxotungstate archetype {P4W24}

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Publication details

The article was received on 29 Nov 2017, accepted on 26 Dec 2017 and first published on 02 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC09175C
Citation: Chem. Commun., 2018, Advance Article
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    The homometallic polyoxotungstate archetype {P4W24}

    X. Yi, N. V. Izarova and P. Kögerler, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC09175C

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