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Controlled preparation of amphiphilic triblock-copolyether in a metal- and solvent-free approach for tailored structure-directing agents

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Abstract

Under mild conditions, PPO–PEO–PPO (“reverse Pluronics”) and PBO–PEO–PBO copolyether were generated by way of N-heterocyclic olefin-based organocatalysis. Reverse Pluronics with molar masses > 20 000 g mol−1 could be synthesized with excellent control (ĐM ≤ 1.03) and were converted into (ordered) mesoporous carbons via organic self-assembly to showcase the need for tailor-made copolymer as structure-directing agent.

Graphical abstract: Controlled preparation of amphiphilic triblock-copolyether in a metal- and solvent-free approach for tailored structure-directing agents

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Publication details

The article was received on 24 Nov 2017, accepted on 02 Jan 2018 and first published on 02 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC09031E
Citation: Chem. Commun., 2018, Advance Article
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    Controlled preparation of amphiphilic triblock-copolyether in a metal- and solvent-free approach for tailored structure-directing agents

    A. Balint, M. Papendick, M. Clauss, C. Müller, F. Giesselmann and S. Naumann, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC09031E

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