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A series of unprecedented triol-stabilized [H3MW6O24]n-: the missing piece between A and B type Anderson-Evans polyoxometalates

Abstract

Several novel triol-ligands functionalized Anderson-Evans type polyoxotungstates, K3Na3[{HOCH2C(CH2O)3}AlO3W6O18], K3Na3[{HOCH2C(CH2O)3}CrO3W6O18], K3Na3[{HOCH2C(CH2O)3}CoO3W6O18] and K3Na3[{H3CC(CH2O)3}CoO3W6O18], were successfully synthesized and characterized, in which some of the central metal ions have never been found in the Anderson type polyoxotungstates. The single crystal X-ray diffraction analysis indicated that the clusters were on a status in which only one-side μ3-O was protonated. That means three-protonated cluster is a common type of Anderson cluster aside zero-protonated (A-type) and six-protonated (B-type), which could be named as the T-type.

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Publication details

The article was received on 22 Nov 2017, accepted on 28 Dec 2017 and first published on 02 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC08976G
Citation: Chem. Commun., 2018, Accepted Manuscript
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    A series of unprecedented triol-stabilized [H3MW6O24]n-: the missing piece between A and B type Anderson-Evans polyoxometalates

    Y. Wei and Q. Li, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C7CC08976G

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