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Issue 8, 2018
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Selective hydrogenation of unsaturated aldehydes over Pt nanoparticles promoted by the cooperation of steric and electronic effects

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Abstract

The selective hydrogenation of α,β-unsaturated aldehydes to unsaturated alcohols can reach high selectivity and activity at room temperature using Pt nanoparticles immobilized on a non-porous Al2O3 support stabilized by aspartic acid. Aspartic acid molecules had a significant steric effect on C[double bond, length as m-dash]C hydrogenation and could modify the electronic state of metal particles.

Graphical abstract: Selective hydrogenation of unsaturated aldehydes over Pt nanoparticles promoted by the cooperation of steric and electronic effects

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Publication details

The article was received on 21 Nov 2017, accepted on 02 Jan 2018 and first published on 02 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC08942B
Citation: Chem. Commun., 2018,54, 908-911
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    Selective hydrogenation of unsaturated aldehydes over Pt nanoparticles promoted by the cooperation of steric and electronic effects

    H. Liu, Q. Mei, S. Li, Y. Yang, Y. Wang, H. Liu, L. Zheng, P. An, J. Zhang and B. Han, Chem. Commun., 2018, 54, 908
    DOI: 10.1039/C7CC08942B

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