Issue 4, 2018

An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO2 fixation into cyclic carbonate

Abstract

A mesoporous cationic Cr-MOF, termed FJI-C10, containing imidazolium moieties, Lewis acidic Cr3+ sites and free halogens is constructed for the first time by a topology-guided one-pot synthesis. FJI-C10 exhibits excellent performances in CO2 adsorption (20.2 wt% at 273 K and 1 bar) and chemical fixation of CO2 into cyclic carbonates without the use of co-catalyst under atmospheric pressure.

Graphical abstract: An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO2 fixation into cyclic carbonate

Supplementary files

Article information

Article type
Communication
Submitted
09 Nov 2017
Accepted
21 Nov 2017
First published
21 Nov 2017

Chem. Commun., 2018,54, 342-345

An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO2 fixation into cyclic carbonate

J. Liang, Y. Xie, X. Wang, Q. Wang, T. Liu, Y. Huang and R. Cao, Chem. Commun., 2018, 54, 342 DOI: 10.1039/C7CC08630J

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