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Issue 6, 2018
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Thermally activated delayed fluorescence of a Zr-based metal–organic framework

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Abstract

The first metal–organic framework exhibiting thermally activated delayed fluorescence (TADF) was developed. The zirconium-based framework (UiO-68-dpa) uses a newly designed linker composed of a terphenyl backbone, an electron-accepting carboxyl group, and an electron-donating diphenylamine and exhibits green TADF emission with a photoluminescence quantum yield of 30% and high thermal stability.

Graphical abstract: Thermally activated delayed fluorescence of a Zr-based metal–organic framework

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Publication details

The article was received on 08 Nov 2017, accepted on 22 Dec 2017 and first published on 22 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC08595H
Citation: Chem. Commun., 2018,54, 631-634
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    Thermally activated delayed fluorescence of a Zr-based metal–organic framework

    H. Mieno, R. Kabe, M. D. Allendorf and C. Adachi, Chem. Commun., 2018, 54, 631
    DOI: 10.1039/C7CC08595H

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