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Issue 26, 2018
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Multiple aromatic C–H bond activations by a dirhenium carbonyl complex

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Abstract

Multiple aromatic CH activations by a dirhenium complex have provided meta-related dimetallated arene rings in the complexes Re2(CO)8(μ-H)(μ-η2-1,2-μ-η2-3,4-C14H8)Re2(CO)8(μ-H), 3 and Re2(CO)8(μ-H)(μ-η1-1,μ-η1-3-C6H4)Re2(CO)8(μ-H), 4. Both products were characterized structurally by single crystal X-ray diffraction and DFT molecular orbital analyses.

Graphical abstract: Multiple aromatic C–H bond activations by a dirhenium carbonyl complex

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Publication details

The article was received on 07 Nov 2017, accepted on 08 Mar 2018 and first published on 08 Mar 2018


Article type: Communication
DOI: 10.1039/C7CC08556G
Citation: Chem. Commun., 2018,54, 3255-3257
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    Multiple aromatic C–H bond activations by a dirhenium carbonyl complex

    R. D. Adams, P. Dhull and J. D. Tedder, Chem. Commun., 2018, 54, 3255
    DOI: 10.1039/C7CC08556G

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