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Extremely low loading of Ru species on hydroxyapatite as an effective heterogeneous catalyst for olefin epoxidation

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Abstract

We report a new class promising heterogeneous catalyst for olefin epoxidation based on 0.05 wt% Ru species supported on hydroxyapatite, which was prepared through a simple cation-exchange process between RuCl3·nH2O and hydroxyapatite. The new catalyst showed high activity, excellent selectivity and good recyclability for various olefins in the presence of molecular oxygen and iso-butyraldehyde as co-oxidants.

Graphical abstract: Extremely low loading of Ru species on hydroxyapatite as an effective heterogeneous catalyst for olefin epoxidation

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Publication details

The article was received on 07 Nov 2017, accepted on 20 Dec 2017 and first published on 20 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC08554K
Citation: Chem. Commun., 2018, Advance Article
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    Extremely low loading of Ru species on hydroxyapatite as an effective heterogeneous catalyst for olefin epoxidation

    P. Mekrattanachai, J. Liu, Z. Li, C. Cao and W. Song, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC08554K

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