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Issue 6, 2018
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Selective catalytic synthesis of amino-silanes at part-per million catalyst loadings

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Abstract

Platinum(II) complex [Pt(ItBu′)(ItBu)][BArF4] (1a) is a highly active and selective catalyst in the dehydrocoupling of amines and silanes at part-per-million catalyst loadings (up to 10 ppm, 0.001 mol%), achieving the highest TON and TOF numbers reported in the literature (up to 1 mmol scale). NMR studies suggest a process taking place through electrophilic activation of the silane by the platinum species, assisted by an amine.

Graphical abstract: Selective catalytic synthesis of amino-silanes at part-per million catalyst loadings

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Publication details

The article was received on 06 Nov 2017, accepted on 20 Dec 2017 and first published on 21 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC08530C
Citation: Chem. Commun., 2018,54, 619-622
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    Selective catalytic synthesis of amino-silanes at part-per million catalyst loadings

    P. Ríos, M. Roselló-Merino, O. Rivada-Wheelaghan, J. Borge, J. López-Serrano and S. Conejero, Chem. Commun., 2018, 54, 619
    DOI: 10.1039/C7CC08530C

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