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Issue 7, 2018
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A temperature-responsive C2 wagging vibration in Sc2C2@Cs-C82

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Abstract

The Raman spectra reveal molecular vibration information. Here we report a special temperature-dependent C2 wagging vibration at 225 cm−1 in Sc2C2@Cs-C82 by Raman spectroscopy and quantum-chemical calculations, which corresponds to the internal cluster motion in C82. This finding is of great importance in understanding the internal dynamics of metallofullerenes.

Graphical abstract: A temperature-responsive C2 wagging vibration in Sc2C2@Cs-C82

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Publication details

The article was received on 05 Nov 2017, accepted on 20 Dec 2017 and first published on 20 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC08509E
Citation: Chem. Commun., 2018,54, 775-777
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    A temperature-responsive C2 wagging vibration in Sc2C2@Cs-C82

    B. Wu, T. Wang, Z. Zhang, L. Jiang and C. Wang, Chem. Commun., 2018, 54, 775
    DOI: 10.1039/C7CC08509E

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