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Alternating ring-opening metathesis polymerization by Grubbs-type catalysts with N-pentiptycenyl, N-alkyl-NHC ligands

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Abstract

A Grubbs–Hoveyda type catalyst with a N-pentiptycenyl, N-cyclohexyl-NHC ligand provides poly(nbe-alt-coe) with an excellent degree of alternation while lacking significant activity in the homopolymerization of cyclooctene.

Graphical abstract: Alternating ring-opening metathesis polymerization by Grubbs-type catalysts with N-pentiptycenyl, N-alkyl-NHC ligands

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Publication details

The article was received on 03 Nov 2017, accepted on 08 Dec 2017 and first published on 08 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC08476E
Citation: Chem. Commun., 2018, Advance Article
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    Alternating ring-opening metathesis polymerization by Grubbs-type catalysts with N-pentiptycenyl, N-alkyl-NHC ligands

    R. Vasiuta, A. Stockert and H. Plenio, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC08476E

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