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Issue 11, 2018
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Cobalt(II)-catalyzed chelation-assisted C–H iodination of aromatic amides with I2

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Abstract

The cobalt-catalyzed chelation-assisted iodination of aromatic amides using molecular I2 as an iodinating reagent is reported. 8-Amino-5-chloroquinoline functions as an efficient directing group. This mild and air stable catalytic system shows a wide functional group tolerance and improved synthetic accessibility.

Graphical abstract: Cobalt(ii)-catalyzed chelation-assisted C–H iodination of aromatic amides with I2

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Publication details

The article was received on 03 Nov 2017, accepted on 22 Dec 2017 and first published on 03 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC08457A
Citation: Chem. Commun., 2018,54, 1359-1362
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    Cobalt(II)-catalyzed chelation-assisted C–H iodination of aromatic amides with I2

    Y. Kommagalla, K. Yamazaki, T. Yamaguchi and N. Chatani, Chem. Commun., 2018, 54, 1359
    DOI: 10.1039/C7CC08457A

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