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Issue 6, 2018
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Thiomolybdate [Mo3S13]2− nanocluster: a molecular mimic of MoS2 active sites for highly efficient photocatalytic hydrogen evolution

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Abstract

Thiomolybdate [Mo3S13]2− nanoclusters, as a molecular mimic of MoS2 edge sites, showed high efficiency in catalyzing photochemical H2 evolution from a molecular system of Ru(bpy)3Cl2–ascorbic acid (H2A) under visible light irradiation (≥420 nm), providing a turnover number of 1570 and an initial turnover frequency of 335 h−1 for H2 evolution based on the [Mo3S13]2− catalyst.

Graphical abstract: Thiomolybdate [Mo3S13]2− nanocluster: a molecular mimic of MoS2 active sites for highly efficient photocatalytic hydrogen evolution

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Publication details

The article was received on 23 Oct 2017, accepted on 12 Dec 2017 and first published on 12 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC08178B
Citation: Chem. Commun., 2018,54, 603-606
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    Thiomolybdate [Mo3S13]2− nanocluster: a molecular mimic of MoS2 active sites for highly efficient photocatalytic hydrogen evolution

    Y. Lei, M. Yang, J. Hou, F. Wang, E. Cui, C. Kong and S. Min, Chem. Commun., 2018, 54, 603
    DOI: 10.1039/C7CC08178B

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