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Palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane: synthesis of homoallylic boronic esters

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Abstract

A palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane to afford the corresponding homoallylic organoboronic esters with moderate to excellent yields is reported. This novel transformation provides an efficient strategy for the construction of homoallylic organoboronic esters in one step with a broad substrate scope. It is proposed that the palladium-catalyzed oxidative allylic C–H bond activation process may be involved in the catalytic cycle.

Graphical abstract: Palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane: synthesis of homoallylic boronic esters

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Publication details

The article was received on 09 Oct 2017, accepted on 22 Nov 2017 and first published on 22 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC07788B
Citation: Chem. Commun., 2018, Advance Article
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    Palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane: synthesis of homoallylic boronic esters

    C. Li, M. Li, J. Li, W. Wu and H. Jiang, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC07788B

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