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Issue 6, 2018
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Rhodium(III)-catalyzed chemodivergent annulations between N-methoxybenzamides and sulfoxonium ylides via C–H activation

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Abstract

Chemodivergent and redox-neutral annulations between N-methoxybenzamides and sulfoxonium ylides have been realized via Rh(III)-catalyzed C–H activation. The sulfoxonium ylide acts as a carbene precursor, and coupling occurs under acid-controlled conditions, where Zn(OTf)2 and PivOH promote chemodivergent cyclizations.

Graphical abstract: Rhodium(iii)-catalyzed chemodivergent annulations between N-methoxybenzamides and sulfoxonium ylides via C–H activation

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Publication details

The article was received on 06 Oct 2017, accepted on 15 Dec 2017 and first published on 05 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC07753J
Citation: Chem. Commun., 2018,54, 670-673
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    Rhodium(III)-catalyzed chemodivergent annulations between N-methoxybenzamides and sulfoxonium ylides via C–H activation

    Y. Xu, G. Zheng, X. Yang and X. Li, Chem. Commun., 2018, 54, 670
    DOI: 10.1039/C7CC07753J

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