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Radical halogenation-mediated latent–active glycosylations of allyl glycosides

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Abstract

Radical halogenation-mediated glycosylation using allyl glycosides as donors and as acceptors emerges to be an efficient and hither-to unknown glycosylation method, adhering to the concept of the latent–active methodology. Several di- and trisaccharides that possess the allyl moiety at their reducing end are prepared through this new glycosylation methodology.

Graphical abstract: Radical halogenation-mediated latent–active glycosylations of allyl glycosides

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Publication details

The article was received on 19 Sep 2017, accepted on 27 Nov 2017 and first published on 27 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC07332A
Citation: Chem. Commun., 2018, Advance Article
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    Radical halogenation-mediated latent–active glycosylations of allyl glycosides

    R. Pal, A. Das and N. Jayaraman, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC07332A

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