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Simple preparation and highly selective detection of silver ions using an electrochemical sensor based on sulfur-doped graphene and a 3,3′,5,5′-tetramethylbenzidine composite modified electrode

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Abstract

A novel electrochemical sensor based on sulfur (S)-doped graphene (S-Gr) and a 3,3′,5,5′-tetramethylbenzidine (TMB) composite (S-Gr-TMB) modified glassy carbon (GCE) electrode for highly selective quantitative detection of silver ions (Ag+) were fabricated. The S-Gr-TMB composite was first prepared via electrostatic interaction between TMB and S-Gr and then, the composite was coated on the surface of GCE. The resultant S-Gr-TMB/GCE electrode showed a significant voltammetric response to Ag+ at 0.3 V vs. Ag/AgCl due to the synergistic effect of S-Gr and TMB. The sensor showed good linearity from 50 μM to 400 μM with a detection limit of 2.15 μM towards the determination of Ag+. In addition, after the addition of Fe3+ and other metal ions, including Al3+, Ca2+, Cd2+, Co2+, Cu2+, K+, Mg2+, Na+, Ni2+, Pb2+ and Zn2+, in the same concentration, the current signal remained almost unchanged, revealing that the proposed electrochemical sensor exhibited a high selectivity for Ag+, which solves the nonselective problem of TMB as a spectral probe. This enhanced detection performance is attributed to two factors: (1) S-Gr has excellent electrical conductivity; (2) the coupling interactions between Ag–S are speculated to result in strengthened enrichment for Ag and good selective performance.

Graphical abstract: Simple preparation and highly selective detection of silver ions using an electrochemical sensor based on sulfur-doped graphene and a 3,3′,5,5′-tetramethylbenzidine composite modified electrode

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Publication details

The article was received on 25 Dec 2017, accepted on 19 Mar 2018 and first published on 10 Apr 2018


Article type: Paper
DOI: 10.1039/C7AN02084H
Citation: Analyst, 2018, Advance Article
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    Simple preparation and highly selective detection of silver ions using an electrochemical sensor based on sulfur-doped graphene and a 3,3′,5,5′-tetramethylbenzidine composite modified electrode

    Y. Fu, Y. Yang, T. Tuersun, Y. Yu and J. Zhi, Analyst, 2018, Advance Article , DOI: 10.1039/C7AN02084H

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