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Recent Progress on Organic Donor-Acceptor Complexes as Active Elements in Organic Field-Effect Transistors

Abstract

Recently, organic donor-acceptor complexes (co-crystrals) have been strongly explored as active elements in organic field-effect transistors (OFETs) due to their tunable energy level and different stacking modes. The performance of co-crystal based FETs can be enhanced through the design and synthesis of novel complexes, the control of the self-assembling morphology of co-crystals on substrates, and the optimization of the fabrication conditions of devices. In this review, we will summarize the recent progress on the methods to prepare donor (D)-acceptor (A) cocrystals and their films, present their structure–property relationships, and discuss their potential applications in OFETs according to the co-crystals with different acceptors, namely, (a) tetracyanoquinodimethane (TCNQ) and derivatives; (b) fullerene derivatives (such as C60 and C70); and (c) naphthalenediimide and perylenediimide derivatives. Moreoever, Co-crystal based solid solution and their FET performance is also mentioned.

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Publication details

The article was received on 26 Sep 2017, accepted on 07 Nov 2017 and first published on 07 Nov 2017


Article type: Review Article
DOI: 10.1039/C7TC04389A
Citation: J. Mater. Chem. C, 2017, Accepted Manuscript
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    Recent Progress on Organic Donor-Acceptor Complexes as Active Elements in Organic Field-Effect Transistors

    J. Zhang, J. Jin, H. Xu, Q. zhang and W. Huang, J. Mater. Chem. C, 2017, Accepted Manuscript , DOI: 10.1039/C7TC04389A

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