Jump to main content
Jump to site search

Issue 42, 2017
Previous Article Next Article

The role of solid state solvation on the charge transfer state of a thermally activated delayed fluorescence emitter

Author affiliations

Abstract

The influence of solid state solvation is crucial for understanding the device properties of 3rd generation organic light emitting diodes (OLEDs) based upon thermally activated delayed fluorescence (TADF), for which the native environment of the molecular emitter is an amorphous organic thin film. In this work we use quantum chemistry and molecular dynamics to demonstrate that the magnitude of static solid state solvation effects (SSSE) in a molecular excited state depends not only upon the dipole moment of the host, but also its rigidity and the dipole moment of the emitter in its electronic ground state. Subsequently, molecular dynamics is used to study recently observed time-dependent aspects of solvation in TADF emitters. In contrast to the previously proposed guest–host interactions, the origin of these dynamic effects is proposed to be associated with the dispersion of charge transfer (CT) decay times, which are strongly sensitive to structural fluctuations of the emitter. Our findings extend the present understanding of SSSE in the context of 3rd generation OLEDs based upon TADF, which may be exploited to develop new strategies for higher performing devices.

Graphical abstract: The role of solid state solvation on the charge transfer state of a thermally activated delayed fluorescence emitter

Back to tab navigation

Publication details

The article was received on 07 Sep 2017, accepted on 12 Oct 2017 and first published on 12 Oct 2017


Article type: Paper
DOI: 10.1039/C7TC04099G
Citation: J. Mater. Chem. C, 2017,5, 11001-11009
  •   Request permissions

    The role of solid state solvation on the charge transfer state of a thermally activated delayed fluorescence emitter

    T. Northey, J. Stacey and T. J. Penfold, J. Mater. Chem. C, 2017, 5, 11001
    DOI: 10.1039/C7TC04099G

Search articles by author

Spotlight

Advertisements