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Use of chitosan to reinforce transparent conductive cellulose nanopaper

Abstract

Transparent conductive cellulose nanopaper (TCCNP) with excellent mechanical robustness and enhanced chemical stability offers the potential for diverse applications under severely humid conditions. Here, the flexible freestanding TCCNP was successfully designed using TEMPO-oxidized nanocrystalline cellulose (ONC) crosslinked with chitosan (CS) as fibrous skeletons and silver nanowires (AgNWs) as conductive networks. Due to their structural similarity, the CS molecules conjugated with ONC microstructures to form a well crosslinking reaction between ONC and CS, thus effectively improved the mechanical property of TCCNP in dry state and chemical corrosion stability of TCCNP in wet state. With the addition of CS, the mechanical stress of TCCNP (ONC/CS 70/30 w/w) increased from 14.5 MPa to 30.8 MPa, and the sheet resistance maintained largely unchanged after immersed in the strong acidic solution, alkali solution, alkaline salt solution, and neutral salt solution for 180 min, respectively. Furthermore, the excellent transparent conductive performances of the well-constructed TCCNP with weight ratio of ONC/CS (70/30 w/w) has achieved a low sheet resistance of 4.43 ohm sq−1 at high transparency (89.56%@550nm). The discovery will open the way for further development high-end flexible paper-electronics using the polysaccharides-based TCCNP with high performances.

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Publication details

The article was received on 31 Aug 2017, accepted on 28 Nov 2017 and first published on 29 Nov 2017


Article type: Paper
DOI: 10.1039/C7TC03980H
Citation: J. Mater. Chem. C, 2017, Accepted Manuscript
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    Use of chitosan to reinforce transparent conductive cellulose nanopaper

    H. Zhang, L. Shi and X. Feng, J. Mater. Chem. C, 2017, Accepted Manuscript , DOI: 10.1039/C7TC03980H

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