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High-Performance Wide-Bandgap Copolymers Based on Indacenodithiophene and indacenodithieno[3,2-b]thiophene Units

Abstract

In this work, we demonstrated the synthesis and characterization of two novel donor-acceptor type conjugated polymers, IDT-T1 and IDTT-T1, which consist of indacenodithiophene (IDT) and indacenodithieno[3,2-b]thiophene (IDTT) donor and 1,3-bis(5-bromothiophen-2-yl)-5,7-bis(2-ethylhexyl)-4H,8H-benzo[1,2-c:4,5-c’]dithiophene-4,8-dione (T1) acceptor building blocks. The resulting copolymers exhibited a wide bandgap about 1.90 eV with comparatively low-lying highest occupied molecular orbital (HOMO) energy level. However, IDTT-T1 with extended fused-ring unit was found to have better coplanarity and higher carrier mobility (0.11 cm2 V-1 s-1). In consequence, organic solar cells employing IDTT-T1 as the donor materials afforded a power conversion efficiency (PCE) of 6.58%, while IDT-T1-based devices yielded a relatively lower PCE of 6.26%.

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Publication details

The article was received on 03 May 2017, accepted on 07 Jul 2017 and first published on 10 Jul 2017


Article type: Paper
DOI: 10.1039/C7TC01909B
Citation: J. Mater. Chem. C, 2017, Accepted Manuscript
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    High-Performance Wide-Bandgap Copolymers Based on Indacenodithiophene and indacenodithieno[3,2-b]thiophene Units

    Y. Cai, X. Zhang, X. Xue, D. Wei, L. Huo and Y. Sun, J. Mater. Chem. C, 2017, Accepted Manuscript , DOI: 10.1039/C7TC01909B

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