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Polyhedral Oligomeric Silsesquioxanes (POSSs): An Important Building Block for Organic Optoelectronic Materials

Abstract

Abstract Due to the low-cost, facile processibility and the capability to produce large areas flexible thin films, organic optoelectronic material has been seen as one of the most promising materials in the past two decades in both academic research and industry applications. Particularly, the incorporation of polyhedral oligomeric silsesquioxanes (POSSs) to develop high performance organic optoelectronic materials and the fabrication of these sophisticated materials into highly efficient devices are of significant interests because of the unique hybrid structures and physical properties of POSS. In this review, we present the recent advances in the development of POSS-based organic optoelectronic materials and devices, including organic light-emitting diodes (OLEDs), liquid crystal display, sensors and electrochromic devices. In addition, the insights on the uniqueness of POSS in microstructure, confined size effect and its different organic substituents in the enhancement of the optoelectronic performance are provided. Finally, perspectives and challenges related to the further advancement of POSS-based organic optoelectronic materials are discussed, followed by the proposed design considerations to address the challenges that we are facing in the future.

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Publication details

The article was received on 29 Mar 2017, accepted on 11 May 2017 and first published on 11 May 2017


Article type: Review Article
DOI: 10.1039/C7TC01327B
Citation: J. Mater. Chem. C, 2017, Accepted Manuscript
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    Polyhedral Oligomeric Silsesquioxanes (POSSs): An Important Building Block for Organic Optoelectronic Materials

    Z. Li, J. Kong, F. Wang and C. He, J. Mater. Chem. C, 2017, Accepted Manuscript , DOI: 10.1039/C7TC01327B

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