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Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

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Abstract

A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Electron paramagnetic resonance and transmission electron microscopy confirm the homogeneous dispersion of Al/V in the entire framework. The study of the flexibility by means of CO2 pressure dependent XRPD and high pressure sorption reveals the co-existence of two different large pore phases and a narrow pore phase in the entire pressure regime.

Graphical abstract: Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

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Publication details

The article was received on 14 Sep 2017, accepted on 17 Oct 2017 and first published on 18 Oct 2017


Article type: Communication
DOI: 10.1039/C7TA08103K
Citation: J. Mater. Chem. A, 2017, Advance Article
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    Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

    H. Depauw, I. Nevjestić, G. Wang, K. Leus, F. Callens, E. De Canck, K. De Buysser, H. Vrielinck and P. Van Der Voort, J. Mater. Chem. A, 2017, Advance Article , DOI: 10.1039/C7TA08103K

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