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Issue 32, 2017
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Xe adsorption and separation properties of a series of microporous metal–organic frameworks (MOFs) with V-shaped linkers

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Abstract

A series of microporous metal–organic frameworks (MOFs) constructed by using a V-shaped linker, 4,4′-sulfonyldibenzoic acid, were evaluated for their Xe gas adsorption properties. In particular, a cadmium-based MOF exhibits noteworthy Xe adsorption and separation properties in the presence of other gases under nuclear reprocessing conditions. The outstanding Xe adsorption capacity was attributed to the close pore size matching of the MOF with the kinetic diameter of the Xe atom.

Graphical abstract: Xe adsorption and separation properties of a series of microporous metal–organic frameworks (MOFs) with V-shaped linkers

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Publication details

The article was received on 29 Mar 2017, accepted on 14 Jul 2017 and first published on 15 Jul 2017


Article type: Communication
DOI: 10.1039/C7TA02746J
Citation: J. Mater. Chem. A, 2017,5, 16611-16615
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    Xe adsorption and separation properties of a series of microporous metal–organic frameworks (MOFs) with V-shaped linkers

    D. Banerjee, S. K. Elsaidi and P. K. Thallapally, J. Mater. Chem. A, 2017, 5, 16611
    DOI: 10.1039/C7TA02746J

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