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Benzophenone-based small molecular cathode interlayers with various polar groups for efficient polymer solar cells

Abstract

A series of novel benzophenone-based small molecular cathode interfacial materials with different polar groups including hydroxyl group, neutral amino group, amino N-oxide, and sulfobetaine ion were synthesized for the PTB7:PC71BM-based polymer solar cells between the active layer and Al electrode. The photovoltaic properties of the devices with these interfacial materials were studied. The differences in interface modification performance of hydroxyl and amino interfacial materials were investigated for the first time. The solution-processed devices with the amino N-oxide-based interlayer showed the PCE of 9.34% with the highest short-circuit current density and fill factor by reducing the series resistance and charge recombination compared to the devices with the others in this work. The study of structure–property relationships proposes the significant guidance for the design of efficient cathode interface materials in organic solar cells.

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Publication details

The article was received on 20 Mar 2017, accepted on 19 Apr 2017 and first published on 21 Apr 2017


Article type: Communication
DOI: 10.1039/C7TA02427D
Citation: J. Mater. Chem. A, 2017, Accepted Manuscript
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    Benzophenone-based small molecular cathode interlayers with various polar groups for efficient polymer solar cells

    Z. Liu, W. Li, R. Peng, W. Jiang, Q. Guan, T. Lei, R. yang, A. Islam, Q. Wei and Z. Ge, J. Mater. Chem. A, 2017, Accepted Manuscript , DOI: 10.1039/C7TA02427D

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