Jump to main content
Jump to site search

Issue 17, 2017
Previous Article Next Article

Experimental and theoretical insights into sustained water splitting with an electrodeposited nanoporous nickel hydroxide@nickel film as an electrocatalyst

Author affiliations

Abstract

The execution of the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) requires active, low-cost, and earth-abundant electrocatalysts to realize large-scale water splitting. Herein, by utilization of the electrodeposition technique, a new category of nickel-based materials, i.e. nanoporous nickel hydroxide@nickel (Ni(OH)2@Ni) films on carbon cloth (Ni(OH)2@Ni/CC), has been reported as a Janus electrocatalyst for overall water splitting. The as-deposited Ni(OH)2@Ni/CC exhibited remarkable catalytic performance for the HER in alkaline electrolytes with an overpotential of 68 mV needed to drive the current density of 10 mA cm−2 and much better durability than Pt/C. This film is also efficient for catalyzing the OER in basic media. These films can be employed as catalysts on both the anode and cathode for overall water splitting that approaches 10 mA cm−2 at a cell voltage of 1.58 V, with catalytic stability exceeding those with RuO2 and Pt/C catalysts. Density functional theory calculations further demonstrate that the Ni(OH)2 and Ni in Ni(OH)2@Ni films synergistically favor the chemisorption of hydrogen-containing intermediates, thus leading to highly enhanced water splitting activity.

Graphical abstract: Experimental and theoretical insights into sustained water splitting with an electrodeposited nanoporous nickel hydroxide@nickel film as an electrocatalyst

Back to tab navigation

Supplementary files

Publication details

The article was received on 02 Mar 2017, accepted on 27 Mar 2017 and first published on 29 Mar 2017


Article type: Communication
DOI: 10.1039/C7TA01907F
Citation: J. Mater. Chem. A, 2017,5, 7744-7748
  •   Request permissions

    Experimental and theoretical insights into sustained water splitting with an electrodeposited nanoporous nickel hydroxide@nickel film as an electrocatalyst

    Z. Xing, L. Gan, J. Wang and X. Yang, J. Mater. Chem. A, 2017, 5, 7744
    DOI: 10.1039/C7TA01907F

Search articles by author

Spotlight

Advertisements