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MgCl2/AlCl3 Electrolytes for Reversible Mg Deposition/Stripping: Electrochemical Conditioning or not?

Abstract

To elucidate the discrepancy of electrochemical performance of inorganic MgCl2/AlCl3 electrolytes in ethereal solvents, we conducted a systematic study of MgCl2/AlCl3-DME electrolytes under different conditions. Under optimized conditions, the 1:1 MgCl2/AlCl3 electrolyte in vigorously dried 1, 2-dimethoxyethane (DME) showed unprecedented performance regarding Mg deposition/stripping including reversibility (up to 100% CE), electrolyte conductivity (> 8.5 mS/cm), and anodic stability (3.5 V vs Mg). We showed that water impurity could jeopardize the electrochemical performance of the electrolytes, and adverse influence of water could be recovered through continuous cyclic voltammogram scans, previously known as electrochemical conditioning. The results indicate the cause of the electrochemical conditioning in early studies is attributed to high water level present in electrolytes and highlight that it is critical to carefully control experimental conditions to yield reliable data for Mg electrolytes. A comprehensive discussion of coordination chemistry on MgCl2/AlCl3-DME electrolytes is also present.

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Publication details

The article was received on 26 Feb 2017, accepted on 08 Apr 2017 and first published on 10 Apr 2017


Article type: Communication
DOI: 10.1039/C7TA01769C
Citation: J. Mater. Chem. A, 2017, Accepted Manuscript
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    MgCl2/AlCl3 Electrolytes for Reversible Mg Deposition/Stripping: Electrochemical Conditioning or not?

    S. He, J. Luo and T. Liu, J. Mater. Chem. A, 2017, Accepted Manuscript , DOI: 10.1039/C7TA01769C

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