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Hollandite-type Al-doped VO1.52(OH)0.77 as a zinc ion insertion host material

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Abstract

For the first time, we suggest VO1.52(OH)0.77 and Al-doped VO1.52(OH)0.77 as possible candidate electrode materials for aqueous zinc-ion batteries (ZIBs). Structural analysis data indicate successful doping of Al into the hollandite VO1.52(OH)0.77 tunnel structure, as confirmed by Rietveld refinement of the X-ray diffraction data (XRD) and X-ray absorption near edge structure (XANES) spectroscopy data. Al is preferred to replace V3+, such that the resulting average oxidation state of V increases with increasing Al content in V1−xAlxO1.52(OH)0.77. Electrochemical test results indicate significant improvement in capacity and retention in the Al-doped V1−xAlxO1.52(OH)0.77 due to the presence of strong Al–O bonds, which stabilizes the crystal structure. This is confirmed from the post-cycled data that show less variation in the lattice parameters. Combining the XRD and XANES data, we suggest that the present V1−xAlxO1.52(OH)0.77 is activated by the V4+/3+ redox reaction, accompanied by Zn2+ insertion into the tunnel structure upon reduction and Zn2+ extraction upon oxidation.

Graphical abstract: Hollandite-type Al-doped VO1.52(OH)0.77 as a zinc ion insertion host material

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Publication details

The article was received on 26 Feb 2017, accepted on 05 Apr 2017 and first published on 05 Apr 2017


Article type: Paper
DOI: 10.1039/C7TA01765K
Citation: J. Mater. Chem. A, 2017, Advance Article
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    Hollandite-type Al-doped VO1.52(OH)0.77 as a zinc ion insertion host material

    J. H. Jo, Y. Sun and S. Myung, J. Mater. Chem. A, 2017, Advance Article , DOI: 10.1039/C7TA01765K

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