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A facile immersion-curing approach to surface-tailored poly(vinyl alcohol)/silica underwater superoleophobic coatings with improved transparency and robustness

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Abstract

Oil contamination is problematic in subaqueous environments. It is difficult to prepare long-lasting textured superhydrophilic/underwater oil-repellent coatings without using a sophisticated method. Here, an ultra-facile and low-cost immersion-curing approach has been developed to generate superhydrophilic and underwater superoleophobic coatings from poly(vinyl alcohol) (PVA)/silica (SiO2) nanocomposites. During immersion curing, polymeric dissolution occurs simultaneously with crosslinking but occurs solely at the topmost layer, and helps to create enriched hierarchical surface micro-/nanostructures. Hence, superhydrophilicity is attainable for nanocomposite coatings with a filler percentage of only 15 wt%. Immersion-cured PVA/SiO2 nanocomposite coatings with 35 wt% silica have an excellent underwater superoleophobicity in terms of durability and ultra-low oil adhesion towards a variety of oils, including viscous crude oil. Because of its lower filler content and confined porous structure, this coating has a greater transparency compared with its conventional blend-curing underwater superoleophobic counterpart. Immersion-cured nanocomposite coatings display an excellent mechanical durability based on pencil hardness (3H) and sand-abrasion performance. The extra acrylic/melamine base-coat allows the underwater superoleophobic PVA/SiO2 coatings to be applied to diverse substrates, including glass, metals, and plastics, and renders them free from oil in aqueous environments.

Graphical abstract: A facile immersion-curing approach to surface-tailored poly(vinyl alcohol)/silica underwater superoleophobic coatings with improved transparency and robustness

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Publication details

The article was received on 17 Feb 2017, accepted on 02 Apr 2017 and first published on 03 Apr 2017


Article type: Paper
DOI: 10.1039/C7TA01499F
Citation: J. Mater. Chem. A, 2017, Advance Article
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    A facile immersion-curing approach to surface-tailored poly(vinyl alcohol)/silica underwater superoleophobic coatings with improved transparency and robustness

    Y. Gu, J. Yang and S. Zhou, J. Mater. Chem. A, 2017, Advance Article , DOI: 10.1039/C7TA01499F

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