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Issue 18, 2017
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Ultrasmall Sn nanodots embedded inside N-doped carbon microcages as high-performance lithium and sodium ion battery anodes

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Abstract

Sn based materials are promising anodes both in Li-ion batteries and Na-ion batteries due to their high theoretical capacities (994 mA h g−1 for LIBs and 847 mA h g−1 for SIBs, respectively). In order to improve the cycle performance, Sn/N-doped carbon microcage composites (Sn/NMCs) with Sn nanodots uniformly embedded inside the N-doped carbon microcages are synthesized through a simple spray drying process, followed by thermal treatment. When used as electrodes, Sn/NMCs exhibit an initial reversible capacity of 780 mA h g−1 at 200 mA g−1, and maintain 472 mA h g−1 after 500 cycles in LIBs. For Na-ion batteries, Sn/NMCs deliver an initial reversible capacity of 439 mA h g−1 at 50 mA g−1 and maintain 332 mA h g−1 after 300 cycles. The remarkable electrochemical performance is mainly owing to the advanced structure of Sn/NMCs, which could be attributed to the pore-formation using NaCl, and the grain size inhibition of Sn using N-doped carbon. Moreover, this preparation method is accessible to scale up and can be extended to fabricate other electrode materials.

Graphical abstract: Ultrasmall Sn nanodots embedded inside N-doped carbon microcages as high-performance lithium and sodium ion battery anodes

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Publication details

The article was received on 17 Feb 2017, accepted on 13 Mar 2017 and first published on 14 Mar 2017


Article type: Paper
DOI: 10.1039/C7TA01480E
Citation: J. Mater. Chem. A, 2017,5, 8334-8342
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    Ultrasmall Sn nanodots embedded inside N-doped carbon microcages as high-performance lithium and sodium ion battery anodes

    H. Ying, S. Zhang, Z. Meng, Z. Sun and W. Han, J. Mater. Chem. A, 2017, 5, 8334
    DOI: 10.1039/C7TA01480E

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