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Issue 15, 2017
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In situ coupling of Co0.85Se and N-doped carbon via one-step selenization of metal–organic frameworks as a trifunctional catalyst for overall water splitting and Zn–air batteries

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Abstract

Developing efficient noble metal-free multifunctional electrocatalysts is highly effective to dramatically reduce the overall cost of electrochemical devices. In this work, we demonstrate for the first time a facile strategy for in situ coupling of ultrafine Co0.85Se nanocrystals and N-doped carbon (Co0.85Se@NC) by directly selenizing zeolitic imidazolate framework-67 (ZIF-67) polyhedra. Benefiting from the synergistic effect of the coupling between Co0.85Se and NC, the Co–N–C structure, and the porous conductive carbon network, Co0.85Se@NC affords excellent oxygen evolution reaction (OER) performance with a small overpotential, remarkable stability, and high faradaic efficiency. Furthermore, Co0.85Se@NC can also efficiently catalyze hydrogen evolution reaction (HER) and oxygen reduction reaction (ORR), and we therefore investigated its applications as a trifunctional electrocatalyst for overall water splitting and Zn–air batteries. When used as both the anode and cathode for overall water splitting, a low cell voltage of 1.76 V is sufficient to reach the current density of 10 mA cm−2; the obtained Zn–air batteries exhibit a very low discharge–charge voltage gap (0.80 V at 10 mA cm−2) and long cycle life (up to 180 cycles). These results not only demonstrate a facile strategy for the synthesis of affordable Co0.85Se@NC but also present its huge potential as a trifunctional electrocatalyst for clean energy systems.

Graphical abstract: In situ coupling of Co0.85Se and N-doped carbon via one-step selenization of metal–organic frameworks as a trifunctional catalyst for overall water splitting and Zn–air batteries

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Publication details

The article was received on 16 Feb 2017, accepted on 01 Mar 2017 and first published on 02 Mar 2017


Article type: Paper
DOI: 10.1039/C7TA01453H
Citation: J. Mater. Chem. A, 2017,5, 7001-7014
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    In situ coupling of Co0.85Se and N-doped carbon via one-step selenization of metal–organic frameworks as a trifunctional catalyst for overall water splitting and Zn–air batteries

    T. Meng, J. Qin, S. Wang, D. Zhao, B. Mao and M. Cao, J. Mater. Chem. A, 2017, 5, 7001
    DOI: 10.1039/C7TA01453H

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