Jump to main content
Jump to site search

Issue 15, 2017
Previous Article Next Article

Tuning the wettability of carbon nanotube arrays for efficient bifunctional catalysts and Zn–air batteries

Author affiliations

Abstract

Carbon nanotube arrays (CNTAs) embedded with transition metal oxides (TMOs) have been considered as effective bifunctional catalysts. However, the hydrophobic nature of CNTAs usually limits the wetting of aqueous solutions containing inorganic precursors of TMOs, which results in poor decoration of TMOs on it. Herein, we report a facile strategy to tune the wettability of 3D CNTAs by controlling the nitrogen-doping degree. Particularly, superhydrophilic nitrogen-doped CNTAs (N-CNTAs) were obtained by using pyridine as the reactant, which allows uniform anchoring of cobalt oxide nanoparticles (NPs) on their surface through a simple self-priming freeze-drying assisted immobilization method. The heteroatom-doping and uniformly distributed cobalt oxide NPs endow the obtained hybrid material (Co3O4/N-CNTAs) with excellent OER and ORR performances, which also demonstrated their high efficiency as bifunctional catalysts for Zn–air batteries.

Graphical abstract: Tuning the wettability of carbon nanotube arrays for efficient bifunctional catalysts and Zn–air batteries

Back to tab navigation

Supplementary files

Publication details

The article was received on 07 Dec 2016, accepted on 15 Mar 2017 and first published on 15 Mar 2017


Article type: Paper
DOI: 10.1039/C6TA10505J
Citation: J. Mater. Chem. A, 2017,5, 7103-7110
  •   Request permissions

    Tuning the wettability of carbon nanotube arrays for efficient bifunctional catalysts and Zn–air batteries

    W. Tian, H. Li, B. Qin, Y. Xu, Y. Hao, Y. Li, G. Zhang, J. Liu, X. Sun and X. Duan, J. Mater. Chem. A, 2017, 5, 7103
    DOI: 10.1039/C6TA10505J

Search articles by author

Spotlight

Advertisements