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Optical tracking of relaxation dynamics in semi-dilute hydroxypropylcellulose solutions as a precise phase transition probe

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Abstract

Phase separation of thermo-responsive polymers in solution is a complex process, whose understanding is essential to screen and design materials with diverse technological applications. Here we report on a method based on dynamic light scattering (DLS) experiments to investigate the phase separation of thermo-responsive polymer solutions and precisely define the transition temperature (TPS). Our results are applied on hydroxypropylcellulose (HPC) solutions as an important biosourced green water-soluble polymer. As determined by DLS, the amplitudes of the fast and slow modes of relaxation dynamics evolve as temperature gets closer to the phase transition point eventually leading to phase separation. The evolution of relaxation modes with temperature is markedly different for concentrations below the overlap concentration (c*) (dilute regime), above c* (semi-dilute regime) and above the entanglement concentration (ce). In the three cases though, the fast and slow mode amplitudes undergo a sharp transition in a narrow temperature range, defining accurately the phase separation locus. The results agree with turbidimetric analysis for the phase transition determination but with a better precision. Our results also show that the one-phase dynamics and phase separation dynamics in the two-phase region are only in continuity for c > ce, revealing mechanistic details about the HPC phase separation process. Above TPS we identify a temperature range where the intensity autocorrelation function has a single-exponential shape. In the latter regime, we monitor the growth kinetics of polymer domains and provide clues to rationalize the stabilizing effects of the interfaces leading to the arrested-like phase separation behavior observed for HPC.

Graphical abstract: Optical tracking of relaxation dynamics in semi-dilute hydroxypropylcellulose solutions as a precise phase transition probe

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Publication details

The article was received on 28 Jul 2017, accepted on 07 Sep 2017 and first published on 13 Sep 2017


Article type: Paper
DOI: 10.1039/C7SM01501A
Citation: Soft Matter, 2017, Advance Article
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    Optical tracking of relaxation dynamics in semi-dilute hydroxypropylcellulose solutions as a precise phase transition probe

    H. Garate, K. Li, D. Bouyer and P. Guenoun, Soft Matter, 2017, Advance Article , DOI: 10.1039/C7SM01501A

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