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Issue 41, 2017
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Spherical nematic shells with a prolate ellipsoidal core

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Liquid crystal shells have attracted considerable attention in recent years. In such systems, a combination of confinement and curvature generates topological defect structures that do not exist in the bulk. Past studies, however, have largely focused on perfectly spherical shells, and little attention has been devoted to the impact of core geometry on the configuration and arrangement of topological defects. In this work, a microfluidic glass capillary device is used to encapsulate spherical and prolate ellipsoidal particles in nematic liquid crystal (LC) droplets dispersed in aqueous media. Our experimental studies show that, when trapped inside a radial LC droplet, spherical particles with both homeotropic and planar anchoring are highly localized at the droplet's center. While the radial configuration of the LC droplets is not altered by a homeotropic particle, polystyrene particles with strong planar anchoring disturb the radial ordering, leading to a twisted structure. Experiments indicate that off-center particle positions can also arise, in which defects are displaced towards the vicinity of the droplet's surface. In contrast, when prolate ellipsoidal particles are encapsulated in a thick radial LC shell, the minimum free energy corresponds to configurations where the particle is positioned at the droplet center. In this case, defects arise at the two ends of the prolate ellipsoid, where the curvature of the particle is maximal, leading to the formation of peculiar hybrid and twisted structures.

Graphical abstract: Spherical nematic shells with a prolate ellipsoidal core

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The article was received on 14 Jul 2017, accepted on 21 Sep 2017 and first published on 21 Sep 2017

Article type: Paper
DOI: 10.1039/C7SM01403A
Citation: Soft Matter, 2017,13, 7465-7472
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    Spherical nematic shells with a prolate ellipsoidal core

    M. Sadati, Y. Zhou, D. Melchert, A. Guo, J. A. Martinez-Gonzalez, T. F. Roberts, R. Zhang and J. J. de Pablo, Soft Matter, 2017, 13, 7465
    DOI: 10.1039/C7SM01403A

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