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Light-Responsive Azo-Containing Organogels

Abstract

While azo compounds are widely employed as radical initiators, they have rarely been used as stimuli-responsive motifs in macromolecular constructs. In this study, an azo-based cross-linker was prepared and reacted with with poly(vinyl alcohol) to afford a series of stimuli-responsive organogels. Irradiation of these materials with UV light causes de-crosslinking and triggers a solid-to-liquid phase transition. Model adhesives with de-bonding-on-demand capability based on this design were explored.

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Publication details

The article was received on 24 Mar 2017, accepted on 16 May 2017 and first published on 18 May 2017


Article type: Communication
DOI: 10.1039/C7SM00601B
Citation: Soft Matter, 2017, Accepted Manuscript
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    Light-Responsive Azo-Containing Organogels

    M. A. Ayer, S. Schrettl, S. Balog, Y. C. Simon and C. Weder, Soft Matter, 2017, Accepted Manuscript , DOI: 10.1039/C7SM00601B

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