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Thermo-electrochemical Cells Empowered by Selective Inclusion of Redox-active Ions by Polysaccharides

Abstract

Thermo-electrochemical cells (TECs) are a class of thermoelectric materials that offer high thermoelectric voltage (Seebeck coefficient) with potentially lower costs compared to the conventional thermoelectric materials. To maximize the potential of TECs, we show that the Seebeck coefficient of TECs with a redox pair of I–/I3– is enhanced by introducing polymer–ion interactions. Starch and polyvinylpyrrolidone (PVP) are employed as polymeric hosts for I3– ions. The effective concentration of free I3– ions in the cold cell decreases due to their selective inclusion in host polymers, resulting in the increase of [I–]/[I3–] ratio. Meanwhile in the higher temperature cell, the inclusion of I3– ions by host polymers is less effective and the [I–]/[I3–] ratio is mostly determined by the intrinsic equlibrium without polymers. Consequently, the two electrode cells differing in temperature show a considerable difference in the concentration of I3– ions, which causes a significant increase of the Seebeck coefficient up to 1.5 mVK−1. The performance of polymer TECs can be tuned depending on the polymer-I3- interactions, and starch showed notable performance as compared to PVP, with increased output power by a factor of two.

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Publication details

The article was received on 25 Sep 2017, accepted on 02 Dec 2017 and first published on 04 Dec 2017


Article type: Paper
DOI: 10.1039/C7SE00470B
Citation: Sustainable Energy Fuels, 2017, Accepted Manuscript
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    Thermo-electrochemical Cells Empowered by Selective Inclusion of Redox-active Ions by Polysaccharides

    H. Zhou, T. Yamada and N. Kimizuka, Sustainable Energy Fuels, 2017, Accepted Manuscript , DOI: 10.1039/C7SE00470B

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