Jump to main content
Jump to site search

Issue 3, 2017
Previous Article Next Article

Ultrahigh stability of high-power nanofibrillar PEDOT supercapacitors

Author affiliations

Abstract

Keeping pace with the increasing energy demand, the scientific community continues to develop superior energy storage technologies by expanding the field of nanostructured organic electronics and by engineering advanced electrochemical capacitors. Here, we demonstrate enhanced performance of a nanofibrillar electrochemical capacitor from a conducting polymer, poly(3,4-ethylenedioxythiophene) (PEDOT), conformally deposited on a substrate via evaporative vapour phase polymerization (EVPP). The synthesis grafts polymer nanofibers to aromatic groups on a carbon paper current collector via Friedel–Crafts alkylation utilizing iron chloride oxidant facilitated by nitromethane as a catalyst activator. By grafting EVPP-PEDOT, our devices attain remarkable stability, retaining 90% of their initial capacitance over 350 000 cycles in 1 M H2SO4 at 5 A g−1 current density in a 1 V window; at 10 A g−1, 90% of the capacitance is retained over 200 000 cycles. Besides showing ultra-high stability, these devices possess high power density (25 kW kg−1 at 1 V and 30 kW kg−1 at 1.2 V) with a respective energy density of 4.3 W h kg−1 and 4.9 W h kg−1, as well as a 0.8 Ω minimal electrochemical series resistance that enables fast charge–discharge rates. For applications requiring high energy densities, 5.8 W h kg−1 at 1 V and 7.6 W h kg−1 at 1.2 V are obtained at power densities of 500 W kg−1, 1 V and 550 W kg−1, 1.2 V respectively. This work proposes a synthetic mechanism for the deposition of nanofibrillar PEDOT that controls device performance and demonstrates stable energy storage technology with high power density.

Graphical abstract: Ultrahigh stability of high-power nanofibrillar PEDOT supercapacitors

Back to tab navigation

Supplementary files

Publication details

The article was received on 31 Jan 2017, accepted on 07 Mar 2017 and first published on 27 Mar 2017


Article type: Paper
DOI: 10.1039/C7SE00057J
Citation: Sustainable Energy Fuels, 2017,1, 482-491
  •   Request permissions

    Ultrahigh stability of high-power nanofibrillar PEDOT supercapacitors

    S. Acharya, L. M. Santino, Y. Lu, H. Anandarajah, A. Wayne and J. M. D'Arcy, Sustainable Energy Fuels, 2017, 1, 482
    DOI: 10.1039/C7SE00057J

Search articles by author

Spotlight

Advertisements