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Issue 12, 2017
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Abnormal room temperature phosphorescence of purely organic boron-containing compounds: the relationship between the emissive behaviorand the molecular packing, and the potential related applications

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Abstract

Purely organic materials with the characteristic of room-temperature phosphorescence (RTP) under ambient conditions demonstrate potential benefits in advanced optoelectronic applications. Exploration of versatile and efficient RTP compounds with low prices is full of challenges due to the slow intersystem crossing process and ultrafast deactivation of the active excited states of organic compounds. Here, a series of boron-containing phosphors were found to present RTP with long-lived lifetimes. Among these commercially available and cheap compounds, (4-methoxyphenyl)boronic acid (PBA-MeO) exhibits long-lived RTP, with a lifetime of 2.24 s, which is among the longest lifetimes of single-component small molecules. Our extensive experiments illustrate that both a rigid conformation and expanded conjugation induced by molecular alignment contribute to the persistent RTP. Because of strong intermolecular interactions via hydrogen bonds, these arylboronic acids easily form crystals and are quite appropriate for anti-forgery materials. Subsequently, we develop a precise, speedy and convenient inkjet printing technology for the fabrication of optoelectronic displays. Furthermore, PBA-MeO is used as an additive to feed Bombyx mori silkworms and shows low toxicity over inorganic materials. Our findings may pave a new way for the development of RTP phosphors and promote their use in practical applications.

Graphical abstract: Abnormal room temperature phosphorescence of purely organic boron-containing compounds: the relationship between the emissive behaviorand the molecular packing, and the potential related applications

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Publication details

The article was received on 19 Sep 2017, accepted on 09 Oct 2017 and first published on 09 Oct 2017


Article type: Edge Article
DOI: 10.1039/C7SC04098A
Citation: Chem. Sci., 2017,8, 8336-8344
  • Open access: Creative Commons BY-NC license
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    Abnormal room temperature phosphorescence of purely organic boron-containing compounds: the relationship between the emissive behaviorand the molecular packing, and the potential related applications

    Z. Chai, C. Wang, J. Wang, F. Liu, Y. Xie, Y. Zhang, J. Li, Q. Li and Z. Li, Chem. Sci., 2017, 8, 8336
    DOI: 10.1039/C7SC04098A

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