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Cross-linking Zr-based metal–organic polyhedra via postsynthetic polymerization

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Abstract

Metal organic polyhedra (MOPs) have potential as supramolecular building blocks, but utilizing MOPs for postsynthetic polymerization has not been explored. Although MOPs with flexible organic moieties have been recently reported to target enhanced processability, permanent porosity has not been demonstrated. Here, a novel synthetic strategy involving the cross-linking of MOPs via a covalent bond is demonstrated by exploiting a condensation reaction between the MOP and flexible organic linkers. An amine-functionalized Zr-based MOP is cross-linked with acyl chloride linkers in the crystalline state to form cross-linked MOPs. The condensation reaction results in a cross-linked system without significant changes to the structure of the Zr-based MOP. Such cross-linked MOPs provide a microporous tetrahedral cage based on gas sorption analysis. This cross-linking strategy highlights the potential of MOPs as building blocks and provides access to a new class of porous material.

Graphical abstract: Cross-linking Zr-based metal–organic polyhedra via postsynthetic polymerization

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Publication details

The article was received on 02 Sep 2017, accepted on 22 Sep 2017 and first published on 25 Sep 2017


Article type: Edge Article
DOI: 10.1039/C7SC03847J
Citation: Chem. Sci., 2017, Advance Article
  • Open access: Creative Commons BY-NC license
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    Cross-linking Zr-based metal–organic polyhedra via postsynthetic polymerization

    D. Nam, J. Huh, J. Lee, J. H. Kwak, H. Y. Jeong, K. Choi and W. Choe, Chem. Sci., 2017, Advance Article , DOI: 10.1039/C7SC03847J

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