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Hollowing Out MOFs: Hierarchical Micro- and Mesoporous MOFs with Tailorable Porosity via Selective Acid Etching

Abstract

We report a new strategy for the synthesis of robust hierarchical micro- and mesoporous MOFs from water stable MOFs via a selective acid etching process. The process is controlled by the size-selective diffusion of acid molecules through the MOF windows. This method enables the fine-tuning of the porosity of hierarchical MOFs, allowing for the generation of well-defined mesopores with high mesopore volume. Because of the size-selective diffusion of acid molecules, the inherent crystallinity and external morphology of the resulting MOFs are well-maintained after acid treatment. This novel strategy may provide an alternate route towards the synthesis of diverse hierarchical MOFs.

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Publication details

The article was received on 30 Jun 2017, accepted on 08 Aug 2017 and first published on 09 Aug 2017


Article type: Edge Article
DOI: 10.1039/C7SC02886E
Citation: Chem. Sci., 2017, Accepted Manuscript
  • Open access: Creative Commons BY license
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    Hollowing Out MOFs: Hierarchical Micro- and Mesoporous MOFs with Tailorable Porosity via Selective Acid Etching

    J. Koo, I. Hwang, X. Yu, S. Saha, Y. Kim and K. Kim, Chem. Sci., 2017, Accepted Manuscript , DOI: 10.1039/C7SC02886E

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